Publication of Takahashi laboratory homepage

北海道大学触媒科学研究所 有機合成触媒分野



2016

2016 (12.08 update)

Formation of Seven-Membered Carbocycles via 7-endo Mode Cyclization of Lithioheptatrienes
Kanno, K.; Igarashi, E.; Mizukami, Y.; Nakajima, K.; Song, Z.; Takahashi, T.
Org. Lett. 2016, 18, 6217-6219.

Separation of Five Linearly Aligned Carbons into Two-Carbon and Three-Carbon Groups on Titanium
Song, Z.; Hsieh, Y.-F.; Nakajima, K.; Kanno, K.; Takahashi, T.
Organometallics, 2016, 35, 1092-1097.

Kinetic Resolution of Planar-Chiral Ferrocenylphosphine Derivatives by Molybdenum-Catalyzed Asynmmetric Ring-Closing Metathesis and Their Application in Asynmmetric Catalysis
Ogasawara, M.; Arae, S.; Watanabe, S.; Nakajima, K.; Takahashi, T.
ACS. Catal. 2016, 6, 1308-1315.

2015

2015

Halogen Exchange Reaction of Aliphatic Fluorine Compounds with Organic Halides as Halogen Source
Mizukami, Y.; Song, Z.; Takahashi, T.
Org. Lett. 2015, 17, 5942-5945.

Ring-Closing Metathesis of (η5-Alkenylcyclopentadienyl)(alkenylphosphine)manganese(I) Dicarbonyl Complexes
Tseng, Y.-Y.; Kamikawa, K.; Wu, Q.; Takahashi, T.; Ogasawara, M.
Adv. Synth. Catal. 2015, 357, 2255-2264.

Enantioselective Synthesis of Planar-Chiral Ferrocene-Fused 4-Pyridones and Their Application in Construction of Pyridine-Based Organocatalyst Library
Ogasawara, M.; Wada, S.; Isshiki, E.; Kamimura, T.; Yanagisawa, A.; Takahashi, T.; Yoshida, K.
Org. Lett. 2015, 17, 2286-2289.

Enantioselective Synthesis of Macrocyclic Heterobiaryl Derivatives of Molecular Asymmetry by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis
Okayama, Y.; Tsuji, S.; Toyomori, Y.; Mori, A.; Arae, S.; Wu, W.-Y.; Takahashi, T.; Ogasawara, M.
Angew. Chem. Int. Ed. 2015, 54, 4927-4931.

Simultaneous Induction of Axial and Planar Chirality in Arene-Chromium Complexes by Molybdenum-Catalyzed Enantioselective Ring-Closing Metathesis
Kamikawa, K.; Arae, S.; Wu, W.-Y.; Nakamura, C.; Takahashi, T.; Ogasawara, M.
Chem. Eur. J. 2015, 21, 4954-4957.

Enantioselective Desymmetrization of 1,2,3-Trisubstituted Metallocenes by Molybdenum-Catalyzed Asymmetric Intraannular Ring-Closing Metathesis
Arae, S.; Nakajima, K.; Takahashi, T.; Ogasawara, M.
Organometallics 2015, 34, 1197-1202.

Catalytic Asymmetric Synthesis of Planar-Chiral Transition-Metal Complexes
Arae, S.; Ogasawara, M.
Tetrahedron Lett. 2015, 56, 1751-1761.

2014

2014

Phosphine Oxide-Catalyzed Enantioselective Intramolecular Aldol Reaction via Regioselective Enolization of Unsymmetrical Diketones with Tetrachlorosilane
Kotani, S.; Aoki, S.; Sugiura, M.; Ogasawara, M.; Nakajima, M.
Org. Lett. 2014, 16, 4802-4805.

Coupling of Titanacyclopentadienes with a Cp Ligand and Elimination of One Substituent
Mizukami, Y.; Li, H.; Nakajima, K.; Song, Z.; Takahashi, T.
Angew. Chem. Int. Ed. 2014, 53, 8899-8903.

Phosphine-Olefin Ligands Based on a Planar-Chiral (π-Arene)chromium Scaffold: Design, Synthesis, and Application in Asymmetric Catalysis
Ogasawara, M.; Tseng, Y.-Y.; Arae, S.; Morita, T.; Nakaya, T.; Wu, W.-Y.; Takahashi, T.; Kamikawa, K.
J. Am. Chem. Soc.
2014, 136, 9377-9384.

Efficient Synthesis of Tetrahydroquinolines from the Reaction of Aldehyde, Aniline, and Alkene under the In Situ Redox of SnCl2 and FeCl3
Guo, Q.; Teng, W.; Ren, S.; Rao, S.; Wang, Y.; Chen. L.; Shen, B.; Takahashi, T.
J. Heterocyclic Chem. 2014, 51, 1100-1105.

Hybrid Sponge Comprised of Galactosylated Chitosan and Hyaluronic Acid Mediates the Co-culture of Hepatocytes and Endothelial Cells
Shang, Y.; Tamai, M.; Ishii R.; Nagaoka, N.; Yoshida, Y.; Ogasawara, M.; Yang, J.; Tagawa, Y.
J. Biosci. Bioeng. 2014, 117, 99-106.

2013

2013

Atropisomeric Chiral Dienes in Asymmetric Catalysis: C2-Symmetric (Z,Z)-2,3-Bis[1-(diphenylphosphinyl)ethylidene]tetralin as Highly Active Lewis-Base Organocatalyst
Ogasawara, M.; Kotani, S.; Nakajima, H.; Furusho, H.; Miyasaka, M.; Shimoda, Y.; Wu, W.-Y.; Sugiura, M.; Takahashi, T.; Nakajima, M.
Angew. Chem. Int. Ed. 2013, 52, 13798-13802.

A Palladium Bipyridyl Complex Grafted onto Nanosized MCM-41 as a heterogeneous Catalyst for Negishi Coupling
Wu, W.-Y.; Lin, T.-C.; Takahashi, T., Tsai, F.-Y.; Mou, C.-Y.
ChemCatChem 2013, 5, 1011-1019.

Kinetic Resolution of Planar-Chiral 1,2-Disubstituted Ferrocenes by Molybdenum-Catalyzed Asymmetric Intraannular Ring-Closing Metathesis
Ogasawara, M.; Arae, S.; Watanabe, S.; Nakajima, K.; Takahashi, T.
Chem.−Eur. J. 2013, 19, 4151-4154.

Synthesis and Characterization of Benzo[b]phosphaferrocene Derivatives
Ogasawara, M.; Arae, S.; Watanabe, S.; Subbarayan, V.; Sato, H.; Takahashi, T.
Organometallics 2013, 32, 4997-5000.

Inter- versus Intraannular Ring-Closing Metathesis on Polyallylferrocenes: Five-Fold RCM within a Single Molecule
Ogasawara, M.; Wu, W.-Y.; Arae, S.; Nakajima, K.; Takahashi, T.
Organometallics 2013, 32, 6593-6598.

MnI2-Catalyzed Dimerization of 2-Hydroxyanthracene
Zhang, S.; Wang, Y.; Song, Z.; Nakajima, K.; Takahashi, T.
Chem. Lett. 2013, 42, 697-699.

Asymmetric Aldol Reaction on Water using an Organocatalyst Tethered on a Thermoresponsive Block Copolymer
Suzuki, N.; Inoue, T.; Asada, T.; Akebi, R. Kobayashi, G.; Rikukawa, M.; Masuyama, Y.; Ogasawara, M.; Takahashi, T.; Thang, S.
Chem. Lett. 2013, 42, 1493-1495.

Enantioselective Morita-Baylis-Hillman Reaction Catalyzed by a Chiral Phosphine Oxide
Kotani, S.; Ito, M.; Nozaki, H.; Sugiura, M.; Ogasawara, M.; Nakajima, M.
Tetrahedron Lett. 2013, 54, 6430-6433.

Aromatic Ring Construction from Zirconocenes and Titanocenes
Li, S.; Takahashi, T.
Transition-Metal-Mediated Aromatic Ring Construction (Tanaka, K.; Ed.), Wiley,2013, 299-320.

2012

2012

Kinetic Resolution of Planar-Chiral (η6-Arene)Chromium Complexes by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis
Ogasawara, M.; Wu, W.-Y.; Arae, S.; Watanabe, S.; Morita, T.; Takahashi, T.; Kamikawa, K.
Angew. Chem. Int. Ed. 2012, 51, 2951-2955.

Preparation of C2-Symmetric Allenes by Palladium-Catalyzed Double Nucleophilic Substitution on 3-Bromopenta-2,4-dienyl Acetate
Ogasawara, M.; Suzuki, M.; Takahashi, T.
J. Org. Chem. 2012, 77, 5406-5410.

Application of Zirconacyclopentadienes (Metal-Heterocycles) and Cross-Coupling for the Convenient Preparative Method of 6,13-Disubstituted Pentacene
Jia, Z.; Li, S.; Nakajima, K.; Kanno, K.; Song, Z.; Takahashi, T.
Heterocycles 2012, 86,1495-1506.

Effects of Silyl Substituents on the Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral (Allenylmethyl)silanes and Their SE2' Chirality Transfer Reactions
Ogasawara, M.; Ge, Y.; Okada, A.; Takahashi, T.
Eur. J. Org. Chem. 2012, 1656-1653.

「面不斉遷移金属錯体の触媒的不斉合成」
荒江 祥永・小笠原正道
有機合成化学協会誌, 2012, 70, 593-605.

2011

2011

Synthesis of Co-oligomers of Thiophene Derivatives from Oligoynes via Zirconacyclopentadiene
Payra, D.; Song, Z.; Kanno, K.; Takahashi, T.
Chem. Lett. 2011, 40, 1447-1449.

Selective Dimerization of Aryl-Substituted Terminal Alkynes on Bis(indenyl)zirconocene Derivatives
Ren, S.; Seki, T.; Necas, D.; Shimizu, H.; Nakajima, K.; Kanno, K.; Song, Z.; Takahashi, T.
Chem. Lett. 2011, 40, 1443-1444.

Ring-Closing Metathesis within Chromium-Coordination Sphere: Facile Access to Phosphine-Chelate (π-Arene)chromium Complexes
Ogasawara, M.; Wu, W.-Y.; Arae, S.; Morita, T.; Watanabe, S.; Takahashi, T.; Kamikawa, K.
J. Organomet. Chem. 2011, 696, 3987-3991.

Dehydro Side Coupling of Substituted Pentacene Derivatives
Li, S.; Jia, Z.; Nakajima, K.; Kanno, K.; Takahashi, T.
J. Org. Chem. 2011, 76, 9983-9987.

Preface. Toward next Nobel Prize
Takahashi, T.
Yuki Gosei Kagaku Kyokaishi 2011, 69, 971.

Homoannular Double Friedel-Crafts Acylation of Phosphametallocenes
Ogasawara, M.; Ogura, M.; Sakamoto, T.; Watanabe, S.; Arae, S.; Nakajima, K.; Takahashi, T.
Organometallics 2011, 30, 5045-5051.

Recent Development for Enantioselective Synthesis of Aromatic Compounds from Alkynes via Metallacyclopentadienes
Li, S.; Zhou, L.; Kanno, K.; Takahashi, T.
J. of Heterocyclic Chem. 2011, 48, 517-528.

Preparation of Ssmium η5-Phospholide Complexes and Their Reactions with Acyl Electrophiles: C=O Bond Cleavage and C-C Bond Formation within the Metal Coordination Sphere
Ogasawara, M.; Shintani, M.; Watanabe, S.; Sakamoto, T.; Nakajima, K.; Takahashi, T.
Organometallics 2011, 30, 1487-1492.

Coupling Reaction of a Cyclopentadienyl Ligand with a Dienyl or Alkenyl Moiety on Titanocene
Song, Z.; Hsieh, Y.-F.; Kanno, K.; Nakajima, K.; Takahashi, T.
Organometallics 2011, 30, 844-851.

Preparation of 6,13-Bis(trimethylsilyl)pentacene and Formation of Second-Ring Diels-Alder Adduct of Pentacene
Jia, Z.; Li, S.; Nakajima, K.; Kanno, K.; Takahashi, T.
J. Org. Chem. 2011, 76, 293-296.

2010年以前の論文はこちら→Old Publication